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Molecular iodine in mixture with TBHP presents an highly developed principle for organic and natural synthesis and catalysis by strengthening the selectivity and sustainability of organic transformations. It sales opportunities to the development of metallic no cost greener protocols beneath ambient conditions possibly as a catalytic duo or as a reagent program in blend with an additive. The arrival of this indispensable device led to formation of elaborate organic architectures empowering novel reaction pathways via C–H functionalization, cyclization, cycloaddition, rearrangement, sulfonylation/sulfenylation and oxidation reactions in natural synthesis.
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