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Molecular iodine in mix with TBHP gives an superior concept for natural and organic synthesis and catalysis by improving the selectivity and sustainability of organic and natural transformations. It leads to the improvement of metal free greener protocols below ambient situations possibly as a catalytic duo or as a reagent system in mix with an additive. The advent of this indispensable software led to development of complex organic architectures empowering novel response pathways by using C–H functionalization, cyclization, cycloaddition, rearrangement, sulfonylation/sulfenylation and oxidation reactions in natural and organic synthesis.
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